Electrode Reaction Mechanism of Ag2VO2PO4Cathode

Multistep Surface Electrode Mechanism Coupled with Preceding Chemical Reaction-Theoretical Analysis in Square-Wave Voltammetry

In this theoretical work, we present for the first time voltammetric results of a surface multistep electron transfer mechanism that is associated with a preceding chemical reaction that is linked to the first electron transfer step. The mathematical model of this so-called “surface CEE mechanism” is solved under conditions of square-wave voltammetry. We present relevant set of results portrayi...

Isotopic Separation Factor of Slow Discharge Mechanism of Hydrogen Electrode Reaction. Ii

The Gas Phase Oxidation of Acetaldehyde Reaction Mechanism and Kinetics

The mechanism of the low temperature oxidation of gaseous acetaldehyde was investigated in the temperature range of 1 50-400?°C. The minor, intermediate and major products were identified and measured quantitatively by sampling directly into the ionization chamber of an MS10-C2 mass spectrometer from the reactor. The formation of H2O, CO, CO2, HCOOH, H2, HCHO, CH3COOH and CH3OH as the major pro...

Single walled carbon nanotube in the reaction layer of gas diffusion electrode for oxygen reduction reaction

In this paper, the effect of surface area of reaction layers in gas diffusion electrodes on oxygen reduction reaction was investigated. For this purpose, various amounts (0.1, 0.2, 0.3, 0.4, 0.5, 1, 1.5 and zero %wt of total loading of reaction layer) of single walled carbon nanotube (SWCNT) were inserted in the reaction layer. The performance of gas diffusion electrodes for oxygen reduction re...

Reaction/Diffusion at Electrode/Solution Interfaces: The EC2 Reaction

A closed form analytical expression is derived for the normalized current versus potential response expected for a rotating disc electrode in which an initial fast electron transfer reaction is followed by a homogeneous electrochemical reaction which exhibits second order kinetics. The effect of the homogeneous reaction on the shape of the voltammetric response curve is calculated.